Metal-free boron-doped graphene for selective electroreduction of carbon dioxide to formic acid/formate.

نویسندگان

  • Narayanaru Sreekanth
  • Mohammed Azeezulla Nazrulla
  • Thazhe Veettil Vineesh
  • Krishnamurty Sailaja
  • Kanala Lakshminarasimha Phani
چکیده

Herein we report the electrocatalytic activity of boron-doped graphene for the reduction of CO2. Electrolysis takes place at low overpotentials leading exclusively to formate as the product (vis-à-vis benchmark Bi catalyst). Computational studies reveal mechanistic details of CO2 adsorption and subsequent conversion to formic acid/formate.

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عنوان ژورنال:
  • Chemical communications

دوره 51 89  شماره 

صفحات  -

تاریخ انتشار 2015